Theoretical evidence for a paramagnetic ground state of the cluster ion [(η5-C5Me5)3Re3(µ2-O)6]2+
- 1 January 1986
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 11,p. 843-844
- https://doi.org/10.1039/c39860000843
Abstract
The electronic structure of uncapped trinuclear clusters of early transition metals with six µ2 bridging and three terminal arene ligands (η5, η6) has been analysed, a triplet ground state being predicted for the recently synthesized cluster ion [(η5-C5Me5)3Re3(µ2-O)6]2+, at variance with the reported interpretation of n.m.r. data, which indicates diamagnetism.Keywords
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