Space charge, thermal expansion, and pyroelectricity in polymers

Abstract
The nonlinear thermal expansion of an insulating film containing trapped space charge leads to a reversible pyroelectric current. A general expression for the pyroelectric coefficient of such a system which also includes a contribution from a nonuniform dielectric constant is derived. A simplified expression applicable to insulators with small gradients is also derived and used to make an order-of-magnitude estimate of the pyroelectric coefficient of PVF2.

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