Catalytic asymmetric epoxidation with a chiral ruthenium porphyrin and N-oxides
- 1 January 1997
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- No. 16,p. 2265-2266
- https://doi.org/10.1039/a704275b
Abstract
The enantiomerically pure ruthenium porphyrin 3 was synthesized in very high yield by refluxing the porphyrin 2 with Ru(CO) in phenol; its subsequent use in the catalytic asymmetric epoxidation of olefins with 2,6-dichloropyridine N-oxide as terminal oxidant, to afford epoxides in good yields and with enantioselectKeywords
This publication has 0 references indexed in Scilit: