Stepwise electrochemical catalysis of three successive replacements of the carbonyl group by trimethyl phosphite in a tri-iron cluster complex
- 1 January 1982
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 4,p. 243-245
- https://doi.org/10.1039/c39820000243
Abstract
The electrochemically catalysed replacement of the carbonyl ligand by P(OMe)3 in the tri-iron cluster Fe3S2CO8L (L = C3H2S2) proceeds stepwise and leads to the clusters Fe3S2CO8–nL[P(OMe)3]n(n= 1, 2, or 3).Keywords
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