Three-fragment oxidative addition of chloroform-iminium or -amidinium chlorides to Rh I or Pt II substrates; complexes of the secondary carbene CHNMe2
- 1 January 1972
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 14,p. 851-852
- https://doi.org/10.1039/c39720000851
Abstract
Chloroform-iminium or -amidinum chlorides oxidatively add to RhI or PtII compounds to give RhIII or PtIV carbene complexes; of particular interest are the Cr0, Fe0, RhIII, IrIII, and PtIV complexes of the secondary carbene CHNMe2, in which the hydrogen atom attached to C(carbene) is deshielded (τ–1·2 to +0·9).Keywords
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