Photo-oxidation of thallium(I) with the production of hydrogen peroxide
- 1 January 1972
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 17,p. 1918-1920
- https://doi.org/10.1039/dt9720001918
Abstract
Examination of the photolytic destruction of luminescence of aqueous thallium(I) solutions containing chloride has revealed that luminescence is lost through oxidation, following the equation: TlI+ 2H++ O2→ TlIII+ H2O2. Cl– is necessary for the reaction which is assisted by TlIII. Under similar conditions SnII is also oxidised with the production of H2O2. PbII does not react in this way.Keywords
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