Epitaxial YBa2Cu3Ox thin films with x=6–7 by oxygen in-diffusion following laser deposition

Abstract
We have synthesized (001)‐epitaxially grown YBa2Cu3Ox thin films with x=6–7 by laser deposition without post‐annealing. A key point in the control of x is oxygen pressure during rapid cooling following the deposition. The relation between x and oxygen pressure almost agrees with a thermal equilibrium curve at 500 °C. This can be explained by the incorporation of oxygen during the cooling, considering that the oxygen in‐diffusion is enhanced by the fast ab‐plane diffusion in misoriented regions.