Mode-specific chemical branching ratios in the photodissociation of OClO
- 15 August 1993
- journal article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 99 (4) , 3129-3132
- https://doi.org/10.1063/1.465167
Abstract
The chemical identity (i.e., Cl+O2 vs OCl+O) of the products of the photolysis of OClO depends on the vibrational mode excited in the parent molecule. The ratio of OCl:Cl production is enhanced when combination bands associated with antisymmetric stretching are excited in the OClO Ã electronic state.Keywords
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