Infrared, Raman, and magnetic evidence for a4T⇌2E equilibrium in bis[tri-(2-pyridyl)amine]cobalt(II) perchlorate

Abstract
The microsymmetry about the cobalt atom in the title compound is almost exactly octahedral, and the ligand in the complex is not extensively conjugated; nevertheless, a “crossover” situation is shown to exist in this complex, and use of this phenomenon is made in the assignment of its metal–ligand vibrations.
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