Novel synthesis of a doubly cyclometallated diruthenium complex with strongly coupled metal centres
- 1 January 1993
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 18,p. 1444-1446
- https://doi.org/10.1039/c39930001444
Abstract
A novel coupling method by which a ruthenium(II) complex of a 4′-chloro-substituted 2,2′ : 6′,2″-terpyridine is converted to a dinuclear doubly cyclometallated complex is reported; the dinuclear complex can be oxidized to give a strongly coupled mixed-oxidation state RuIIIRuII species.Keywords
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