Stereoselective Cyclization of cis-Decalin Skeleton of Vinigrol via Ketyl-Olefin Coupling Promoted by Samarium(II) Iodide
- 1 November 1996
- journal article
- letter
- Published by Georg Thieme Verlag KG in Synlett
- Vol. 1996 (11) , 1057-1060
- https://doi.org/10.1055/s-1996-5697
Abstract
The cis-decalin ring system of vinigrol, a unique tricyclic diterpene isolated as a novel antihypertensive compound from a culture broth of Virgaria nigra, was synthesized featuring a ketyl-olefin coupling annulation reaction induced by SmI2.Keywords
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