Perturbation calculations of the square well system in the solid phase
- 15 April 1974
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 60 (8) , 3330-3334
- https://doi.org/10.1063/1.1681526
Abstract
The perturbation expansion scheme of Zwanzig is applied to the square well system in the solid phase. The Monte Carlo method is used to calculate the reference system of hard spheres and some isotherms of the square well system. First order perturbation theory reproduces the machine calculated ``quasiexperimental'' equation of state, to a fair degree of accuracy.Keywords
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