Variational eigenvalues for the Rydberg states of helium: Comparison with experiment and with asymptotic expansions
- 26 November 1990
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review Letters
- Vol. 65 (22) , 2769-2772
- https://doi.org/10.1103/physrevlett.65.2769
Abstract
High-precision variational eigenvalues are presented for a range of helium Rydberg states up to n=10 and L=7. Convergence to a few parts in is obtained for many of the nonrelativistic eigenvalues. The results allow a clear assessment of the accuracy of asymptotic expansion methods extensively developed for states of high angular momentum. After adding relativistic and radiative corrections, a comparison with new high-precision measurements for transitions among the n=10 states is made. Contributions from the long-range Casimir-Polder effect are discussed.
Keywords
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