Argon Matrix Raman Spectra of Oxygen Difluoride and the Oxygen Fluoride Free Radical
- 1 July 1972
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 57 (1) , 51-55
- https://doi.org/10.1063/1.1677992
Abstract
The argon matrix Raman spectra of oxygen difluoride and oxygen‐18 difluoride at 16°K have been observed; frequencies within one wavenumber of analogous infrared studies were measured. Laser photo‐detachment of fluorine atoms has provided significant yields of the OF and 18OF free radicals; the Raman observations confirm the earlier infrared work. Temperature cycling operations and depolarization ratio measurements provide aid in identifying new chemical species and making vibrational assignments.Keywords
This publication has 9 references indexed in Scilit:
- Raman and Infrared Spectra of LiO2 in Oxygen MatricesThe Journal of Chemical Physics, 1972
- Depolarization Measurements in Raman Matrix Isolation SpectroscopyThe Journal of Chemical Physics, 1971
- Infrared Spectra of Free Radicals and Chemical Intermediates in Inert MatricesAnnual Review of Physical Chemistry, 1971
- Matrix Infrared Spectrum of OF and Detection of LiOFThe Journal of Chemical Physics, 1971
- The Raman spectrum of liquid oxygen difluoride (OF2)Journal of Molecular Spectroscopy, 1971
- Matrix infrared studies of OF radical systemsThe Journal of Physical Chemistry, 1969
- Labeled oxygen difluoride—O17,18The International Journal of Applied Radiation and Isotopes, 1965
- Matrix Infrared Studies of OF Compounds. I. The OF Radical1Journal of the American Chemical Society, 1965
- Raman Spectrum of FluorineThe Journal of Chemical Physics, 1950