REACTIONS OF CARBONYLSULPHIDE WITH [Rh(PPh3)3CI] AND [Pt(PPh3)3]
- 1 March 1977
- journal article
- research article
- Published by Taylor & Francis in Journal of Coordination Chemistry
- Vol. 6 (4) , 207-209
- https://doi.org/10.1080/00958977708073021
Abstract
Activation of small inorganic molecules (H2, N2, O2, CO, NO, CO2, SO2, CS2) by the complexes of transition metal ions like Rh(I), Ir(I), Pt(O) and Ru(II) have gained considerable interest during the last decade.1–8 Because of the similarity of CO2 and CS2 molecules with COS, one would expect COS to form complexes with the transition metal ions analogous to those of CO2 and CS2. In addition, COS being susceptible to decomposition into CO and S, could also form carbonyl complexes. Until now, the only reaction of COS that has been successfully carried out is with [Pt(PPh3)3] which resulted in the formation of [Pt(COS)(PPh3)2] and [Pt2S(CO) (PPh3)3]. 8,9 It will, therefore, be interesting to study further the reactions of COS with the complexes of transition metal ions. The results of a preliminary study of such reactions with [Rh(PPh3)3Cl] and [Pt(PPh3)3] are reported in this communication.Keywords
This publication has 15 references indexed in Scilit:
- Activation of small molecules by osmium(II) and ruthenium(II) complexesJournal of Inorganic and Nuclear Chemistry, 1974
- Reversible addition of carbon dioxide to rhodium and iridium complexesJournal of the Chemical Society, Chemical Communications, 1974
- Reactions of carbon dioxide with transition metal compoundsPure and Applied Chemistry, 1973
- Reactions of hydrido complexes of ruthenium and rhodium with carbon dioxide involving reversible insertionJournal of Organometallic Chemistry, 1972
- The reactions of organometallic compounds of transition metals with molecular nitrogen and carbon dioxidePublished by Walter de Gruyter GmbH ,1972
- Crystal and molecular structure of µ-sulphido-carbonyltris(triphenylphosphine)diplatinum(II): a complex with a platinum–platinum covalent bondJ. Chem. Soc. A, 1969
- Tris‐ and Tetrakis(Triphenyl‐Phosphine)Platinum (0)Published by Wiley ,1968
- Cationic π-carbon disulphide complexes of rhodium and iridium; thiocarbonyl complexes of iridiumJ. Chem. Soc. A, 1968
- Thiocarbonyl and carbon disulphide complexes of rutheniumJ. Chem. Soc. A, 1968
- Carbon disulphide, carbonyl sulphide, and alkyl and aryl isothiocyanate and perfluorothioacetone complexes of nickel, palladium, platinum, rhodium, and iridiumJ. Chem. Soc. A, 1967