Complete stereoselectivity in the intramolecular Diels–Alder reaction of an ester derived from ‘deacetone glucose’
- 1 January 1984
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 15,p. 1029-1030
- https://doi.org/10.1039/c39840001029
Abstract
The intramolecular Diels–Alder reaction of the ester (3), which is readily obtainable from ‘diacetone glucose,’ gives compound (4) but under the reaction conditions sunstantial 1,3-prototropic shift occurs with the formation of (8).Keywords
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