Upper and lower bounds to atomic and molecular properties. III. Lithium oscillator strengths for variousS2P2transitions

Abstract
Wave functions, which include interelectron coordinates explicitly, are calculated for the four lowest S2 and four lowest P2 states of Lii. These wave functions are used to calculate oscillator strengths, including upper and lower bounds, for the 16 lines arising from allowed transitions among these four S2 and four P2 states. The results of this study are oscillator strengths for the 1s2nsS21s2mpP2 Lii transitions for which n, m=2, 3, 4, 5 with rigorous upper and lower bounds which in the best case (1s22sS21s22pP2) are 3.5%.