Dynamical Jahn-Teller effect on spin-orbit multiplets: intensity quenching

14 September 1979

journal article
Published by IOP Publishing in Journal of Physics C: Solid State Physics

Vol. 12 (17) , L699-L704
https://doi.org/10.1088/0022-3719/12/17/013

Abstract

The intensity quenching operated by the dynamical Jahn-Teller effect on the components of a spin-orbit-split zero-phonon line has been investigated. Comparison with experiment allows for the evaluation of the important microscopic energies entering the problem. The method has been successfully applied to KMgF₃:V²⁺ to find the Jahn-Teller energy and the vibrational quantum of the Jahn-Teller active modes. The validity of the cluster model is discussed.

Keywords

JAHN TELLER

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