High Selectivity in Polymerization of (Z)-1,3-Pentadiene, with the CpTiCl3−MAO Catalytic System, Generated by Backbiting Coordinations of the Growing Polydienyl Chain
- 17 February 2004
- journal article
- Published by American Chemical Society (ACS) in Macromolecules
- Vol. 37 (6) , 2016-2020
- https://doi.org/10.1021/ma035892c
Abstract
No abstract availableThis publication has 25 references indexed in Scilit:
- Stereoselectivity and chemoselectivity in Ziegler–Natta polymerization of conjugated dienes. 2. Mechanism for 1,2 syndiotactic polymerization of diene monomers with high energy s-cis η4 coordinationPolymer, 2004
- Theoretical Investigation of the Mechanism of Cis−Trans Regulation for the Allylnickel(II)-Catalyzed 1,4 Polymerization of ButadieneAccounts of Chemical Research, 2002
- Stereoselectivity and Chemoselectivity in Ziegler−Natta Polymerizations of Conjugated Dienes. 1. Monomers with Low-Energy s-Cis η4 CoordinationMacromolecules, 2001
- Mechanistic Studies of the 1,4-Polymerization of Butadiene According to the π-Allyl-Insertion Mechanism. 3. Density Functional Study of the C−C Bond Formation Reaction in Cationic “Ligand-Free” (η3:η2-Heptadienyl)(η2-/η4-butadiene)nickel(II) Complexes [Ni(C7H11)(C4H6)]+Organometallics, 1999
- Density Functional (DFT) Study of the Anti−Syn Isomerization of the Butenyl Group in Cationic and Neutral (Butenyl)(butadiene)(monoligand)nickel(II) ComplexesOrganometallics, 1999
- Mechanistic Studies of the 1,4-Polymerization of Butadiene According to the π-Allyl-Insertion Mechanism. 2. Density Functional Study of the C−C Bond Formation Reaction in Cationic and Neutral (η3-Crotyl)(η2-/η4-butadiene)nickel(II) Complexes [Ni(C4H7)(C4H6)]+, [Ni(C4H7)(C4H6)L]+ (L = C2H4, PH3), and [Ni(C4H7)(C4H6)X] (X- = I-)Organometallics, 1998
- Chemoselective mechanism of (Z)-1,3-pentadiene polymerization in the presence of cyclopentadienyltitanium trichloride and methylaluminoxaneMacromolecular Chemistry and Physics, 1998
- Copolymerization of 1,3-dienes with CpTiCl3-MAO. Some cases in which the mode of monomer coordination affects the copolymer structureMacromolecular Chemistry and Physics, 1997
- Chemoselectivity in 4‐methyl‐1,3‐pentadiene polymerization in the presence of homogeneous Ti‐based catalystsMacromolecular Rapid Communications, 1997
- Mechanistic Studies of the 1,4-Cis Polymerization of Butadiene According to the π-Allyl Insertion Mechanism. 1. Density Functional Study of the C−C Bond Formation Reaction in Cationic (η3-Allyl)(η2-/η4-butadiene)nickel(II) Complexes [Ni(C3H5)(C4H6)]+ and [Ni(C3H5)(C4H6)(C2H4)]+Organometallics, 1996