Biosynthesis and absolute configuration of diterpene cryptotanshinone from Salvia miltiorrhiza: stereochemistry of methyl migration in the formation of the abietane skeleton determined by incorporation of D-[U-13C6]glucose
- 1 January 1987
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 17,p. 1311-1313
- https://doi.org/10.1039/c39870001311
Abstract
Experimental evidence is presented supporting a hypothetical pathway for the biosynthesis of diterpene cryptotanshinone (1); the stereochemistry of a 1,2-methyl migration in the formation of the abietane skeleton has been determined by incorporation of D-[U-13C6]glucose and determination of the absolute configuration at C-15 of (1).Keywords
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