Synthesis and X-ray crystal structure of the tungsten dimetallatetrahedrane complex[W2Cl4(µ-Cl)2(µ-C2Me2)(THF)2](THF = tetrahydrofuran)
- 1 January 1989
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 7,p. 418-419
- https://doi.org/10.1039/c39890000418
Abstract
Treatment of {[W2Cl7(THF)5]Na} with excess of alkyne gives the dimetallatetrahedrane compounds, [W2Cl4(µ-Cl)2(µ-C2RR′)(THF)2](R = R′= H, Me, Et; R = H, R′= Ph); the X-ray crystal structure of [W2Cl4(µ-Cl)2(µ-C2Me2)(THF)2](1) reveals a confacial bioctahedral co-ordination environment about the ditungsten centre with a bridging alkyne unit.Keywords
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