Oxidative addition of quadricyclene to di-µ-chlorotetracarbonyldirhodium(I) and the mechanism of the rhodium(I)-catalysed isomerization of quadricyclene to norbornadiene
- 1 January 1970
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 17,p. 1082-1083
- https://doi.org/10.1039/c29700001082
Abstract
Several new organorhodium compounds derived from the reaction of quadricyclene with di-µ-chlorotetracarbonyldirhodium(I) are described; it is concluded that the rhodium(I)-catalysed valence isomerization of quadricyclene to norbornadiene proceeds through a non-concerted mechanism involving an oxidative addition step.Keywords
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