Pyrazolyl-Bridged Iridium Dimers. 16.1 The Atropisomeric (C2) System [Ir(CO)(PPh3)(μ-pz)]2. Synthesis of Homologous Diastereomeric Complexes That Undergo Slow Stereomutation by Ring Inversion of the Bridging Framework: Mechanistic Implications for Bimetallic Substrate Activation

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