Removal of arsenic from wastewater using chemical precipitation methods

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Abstract
The use of arsenic in agriculture, industry, and domestic endeavors since the last century has increased the concentration of arsenic in the environment. During cleanup activities at a former pesticide facility, water that was collected during various operations was contaminated with arsenic and required treatment before discharge. Chemical precipitation was identified as being the most effective means of treatment. Bench‐scale treatability testing was completed to determine the effectiveness of various coagulants, including ferric chloride, hydrated lime, sodium sulfide, and alum. A combination of hydrated lime and ferric chloride was able to remove more than 99% of the original arsenic concentration. Contaminated water to be treated by the full‐scale system had arsenic concentrations up to 48 mg/L. The discharge limitation required that the arsenic concentration be reduced to less than 1 mg/L. More than 605 000 L (160 000 gal) of water were treated using a combination of chemical precipitation, filtration, and carbon absorption.

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