Synthesis of 3-Substituted 2,5-Dihydro-2,2,5,5-tetramethyl-1H-pyrrol-1-yloxyl Radicals, Useful for Spin-Labelling of Biomolecules
- 1 January 1989
- journal article
- research article
- Published by Georg Thieme Verlag KG in Synthesis
- Vol. 1989 (07) , 526-529
- https://doi.org/10.1055/s-1989-27306
Abstract
Synthesis and some reactions of 3-substituted 2,5-dihydro-2,2, 5,5-tetramethyl-1H-pyrrol-1-yloxyl radicals (nitroxyl radicals, nitroxides) activated with carbonyl, cyano, or ester electron-withdrawing groups have been described. These compounds are useful new SH-reagents for spin-labelling of biomolecules.Keywords
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