High yields of nitrene insertion into unactivated C–H bonds. First example of X-ray crystallographic and19F NMR analysis of the photochemically produced C–H inserted adduct
- 1 January 1994
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 16,p. 1841-1842
- https://doi.org/10.1039/c39940001841
Abstract
Photolysis of 4-azido-tetrafluorobenzonitrile results in the highest yield reported to date, (75–80% as estimated from 19F NMR spectroscopy) for nitrene insertion into the unactivated C–H bond of cyclohexane; the photochemical adduct is characterized by 1H and 13C NMR spectroscopy and the structure is confirmed by X-ray crystallography for the first time.Keywords
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