Matrix‐assisted laser desorption/ionization mass spectrometry of polysaccharides

Abstract
In this paper we report matrix‐assisted laser desorption/ionization (MALDI) mass spectra of dextrans up to 100 000 Da molecular weight and compare these measurements with those obtained by conventional size‐exclusion chromatography with low‐angle laser light scattering (SEC/LALLS). These results extend the usefulness of MALDI‐MS to higher molecular weight polysaccharides and give some insights into the MALDI process.

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