Length dependence of the second-order optical nonlinearity in conjugated hydrocarbons
- 1 February 1981
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 74 (3) , 1559-1563
- https://doi.org/10.1063/1.441296
Abstract
Experimental results and a theoretical model are presented which give strong evidence that the ratio β/L2μM is a constant for a large class of disubstituted conjugated hydrocarbons, β is the second-order polarizability, μM the mesomeric dipole moment, and L the length of the hydrocarbon chain.Keywords
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