Neuartige, hochstereoselektive Umlagerungen chiraler Dihydropyranone
- 1 December 1979
- journal article
- zuschrift
- Published by Wiley in Angewandte Chemie
- Vol. 91 (12) , 1001-1002
- https://doi.org/10.1002/ange.19790911210
Abstract
Wichtige chirale Synthone sind die von Zuckern abgeleiteten Dihydropyranone vom Typ (1) und (3). Endiolone (3) können nach neuen, ergiebigen Verfahren hergestellt werden. Besonders interessant ist die Umlagerung (3) (2): Es findet ein Chiralitätstransfer von einer Seite des Ringes auf die andere statt. magnified imageKeywords
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