Synthesis and reactivity of (dppe)Pt(OMe)2[dppe = 1,2-bis(diphenylphosphino)-ethane]
- 1 January 1985
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 14,p. 977-978
- https://doi.org/10.1039/c39850000977
Abstract
Synthesis of (dppe)Pt(OMe)2(1)[dppe = 1,2-bis(diphenylphosphino)ethane] by NaOMe metathesis on the analogous dichloride is reported along with the thermal and carbonylation chemistry of (1); the release of dimethyl carbonate and dimethyl oxalate from the carbonylation product (dppe)Pt(CO2Me)2 was accomplished by thermal and oxidative techniques.Keywords
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