Nucleosides. Part VI. The formation of anomeric nucleosides from the silver salt of hypoxanthine
- 1 January 1968
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society C: Organic
- Vol. 15, 1929-1933
- https://doi.org/10.1039/j39680001929
Abstract
The silver salt of hypoxanthine condenses with 2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl bromide in xylene to give a mixture of products which after deacetylation and separation yielded both α- and β-anomers of 7- and 9-D-glucopyranosylhypoxanthine. In addition several substituted imidazoles are produced which are formed from various N1-substituted hypoxanthines under the alkaline conditions used in the separation.Keywords
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