Olefin insertion into the platinum—hydrogen bond
- 1 January 1971
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 16,p. 957-958
- https://doi.org/10.1039/c29710000957
Abstract
Ready insertion of ethylene of propene into the Pt–H bond of PtII hydrido–complexes, which leads to good yields of ethyl or n-propyl derivatives, involves displacement of the ligand trans to the hydridic hydrogen in a cationic species, giving a cationic hydrido-olefin complex as intermediate.Keywords
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