The “Facilitated Transition” hypothesis as an explanation for the gemdialkyl effect
- 1 October 1996
- journal article
- Published by Elsevier in Journal of Molecular Structure: THEOCHEM
- Vol. 370 (2-3) , 187-202
- https://doi.org/10.1016/s0166-1280(96)04701-x
Abstract
No abstract availableThis publication has 27 references indexed in Scilit:
- Rate acceleration of the intramolecular diels-alder reaction with furan-diene by anchoring substitution : The t-butyl effect revisited.Tetrahedron Letters, 1993
- gem-Dialkyl effect in the intramolecular Diels-Alder reaction of 2-furfuryl methyl fumarates: the reactive rotamer effect, the enthalpic basis for acceleration, and evidence for a polar transition stateJournal of the American Chemical Society, 1991
- Synthetic and kinetic studies of the intramolecular Diels-Alder reactions of cycloalkenylallenylphosphine oxidesThe Journal of Organic Chemistry, 1990
- Effects of Variations of Alkoxy Substituents upon Cyclizations of Dialkoxy-2-chloroethylsilyl Enol Ethers to form 2,2-Dialkoxy-1-oxa-2-silacyclohexanesChemistry Letters, 1990
- Solvent effects in intramolecular Diels-Alder reactions of 2-furfuryl methyl fumarates: evidence for a polar transition stateJournal of the American Chemical Society, 1989
- Studies on the effects of substituents on rate enhancements in intramolecular diels-alder reactions: Reasons for the gem-dimethyl effectTetrahedron Letters, 1988
- Intramolecular Diels-Alder reactions with furan: The gem-dialkyl effect revisitedTetrahedron Letters, 1985
- Intramolecular diels-alder reactions of the furan diene: substituent and solvent effectsTetrahedron Letters, 1982
- Comparison of stereopopulation control with conventional steric effects in lactonization of hydrocoumarinic acidsJournal of the American Chemical Society, 1976
- Steric acceleration of lactonization reaction: an analysis of "stereopopulation control"Journal of the American Chemical Society, 1976