Synthesis and structure of arene soluble N,N′-bis(di-tert-butylsalicylidene)ethylenediamine yttrium complexes
- 1 January 1999
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 4,p. 311-312
- https://doi.org/10.1039/a807470d
Abstract
YCl3 reacts with 1 and 2 equiv. of the dipotassium saltof N,N′-bis(3,5-di-tert-butylsalicylidene)ethylenediamine (K2salen′) and thf to form the arene soluble complexes, [(salen′)Y(µ-Cl)(thf)]2 and (thf)2K[Y(salen′)2], respectively, which provide comparative structural information on the use of this ligand vis-à-vis bis(cyclopentadienyl) ligand sets.Keywords
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