Tricarbollides—compounds of the eleven-vertex series of tricarbaboranes
- 1 January 1995
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 7,p. 795-796
- https://doi.org/10.1039/c39950000795
Abstract
Alternative syntheses of the zwitterionic compounds 7-L-nido-7,8,9-C3B8H10(where L = H2N–, Me3N, and ButNH2) are reported from reactions involving the [indo-5,6-C2B8H11]– anion, the CN– anion and/or alkyl isocyanides RNC (for R = But); deamination of the Me3N derivative leads to the first unsubstituted eleven-vertex tricarbaboranes nido-7,8,9-C3B8H12 and [nido-7,8,9-C3B8H11]–.Keywords
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