Facile synthesis of first generation ferrocene dendrimers by a convergent approach using ditopic conjugated dendronsElectronic supplementary information (ESI) available: molecular structure of 2. See http://www.rsc.org/suppdata/nj/b1/b108142j/
- 28 February 2002
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in New Journal of Chemistry
- Vol. 26 (3) , 291-297
- https://doi.org/10.1039/b108142j
Abstract
A facile synthesis of new conjugated ferrocenyl-based dendrimers is reported and the compounds obtained have been fully characterized. The synthetic method consists of a two-step procedure, which combines olefination by the Wittig procedure and Pd-mediated C–C coupling, leading to high yields of first generation dendrimers with 3, 6 and 12 peripheral ferrocene units. The crystal structure of the conjugated ditopic ferrocenyl dendron and its aldehyde precursor are also described.Keywords
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