Motion in solid organotin(IV) coordination polymers: a two-dimensional exchange magic angle spinning 13C NMR study
- 1 January 1992
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 10,p. 740-741
- https://doi.org/10.1039/c39920000740
Abstract
Solid-state 13C CP MAS NMR studies of compounds [(Me3Sn)4M(CN)6]∞ with M = Fe, Ru and Os, using variable temperature, show that the trigonal bipyramidal arrangements at Sn are undergoing internal rotation about the N-Sn-N axes with lifetimes of the order of 0.5 s at moderately lowered temperature.Keywords
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