Diketen as a butenoic acid synthon in regioselective olefin syntheses
- 1 January 1977
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 14,p. 500-501
- https://doi.org/10.1039/c39770000500
Abstract
The adduct (2) between diketen (1) and Me3SiCH2MgCl is a versatile methylbutenoic (isoprenoid) acid synthon in allylation with prenyl bromide, in δ-lactone formation with several carbonyl compounds, and in palladium-mediated alkylation.Keywords
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