Enthalpy of formation of oxalyl chloride and the COCl radical
- 1 January 1967
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Transactions of the Faraday Society
- Vol. 63, 879-882
- https://doi.org/10.1039/tf9676300879
Abstract
The heat of formation for liquid oxalyl chloride has been determined by reaction calorimetry to be –85.6 ± 0.5 kcal/mole. From this it is deduced that ΔH° f298 oxalyl chloride (g)=– 78.0 ± 1.4 kcal/mole and ΔH° f298(COCl,g)=–4.0 ± 3 kcal/mole.Keywords
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