In situ synthesis of phenyltrithiophosphonate: isolation and structure of [PPh4]2[W2S4{S2(S)PPh}2]
- 1 January 1990
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 3,p. 281-282
- https://doi.org/10.1039/c39900000281
Abstract
PhP(S)S2 2– has been prepared directly by the reaction of [PPh4]2[WS4] with PhPCl2; [PPh4]2[W2S4{S2(S)PPh}2] has been isolated and the anion shown to involve a W2S4 core to which are ligated two bidentate PhP(S)S2 moieties.Keywords
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