Vibration-rotation spectroscopy of the CrH radical in its X6Σ+ground state by CO-Faraday laser magnetic resonance
- 10 August 1991
- journal article
- research article
- Published by Taylor & Francis in Molecular Physics
- Vol. 73 (5) , 1041-1050
- https://doi.org/10.1080/00268979100101751
Abstract
We report the first direct observation of the vibration-rotation spectrum of the diatomic chromium-hydride in its X6Σ+ ground state by CO-Faraday laser magnetic resonance spectroscopy (LMR). Transitions of all four isotopomers attributed to the fundamental and the first hot band were detected. The spectra were analysed by a single least-squares fit using an effective Hamiltonian. A set of effective molecular parameters for the X6Σ+ ground state is given.Keywords
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