AB Initio Calculations for Helium-4 of Thermodynamic and Transport Properties of the Gas and the Ground State Energy of the Liquid
Open Access
- 1 January 1972
- journal article
- research article
- Published by CSIRO Publishing in Australian Journal of Physics
- Vol. 25 (6) , 735-742
- https://doi.org/10.1071/ph720735
Abstract
A potential energy curve for the 4He diatom obtained from a perturbation theory solution of the Schr�dinger equation is used to calculate the viscosity, thermal conductivity, self-diffusion coefficient, and second virial coefficient of gaseous 4He. In addition, the ground state energy of the zero-temperature liquid is obtained by a variation procedure using a trial wavefunction in conjunction with the Monte Carlo method. The results are in good agreement with experiment.Keywords
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