Model for the Electronic Structure of Metal Tungsten Bronzes
- 15 April 1963
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 38 (8) , 1991-1998
- https://doi.org/10.1063/1.1733908
Abstract
The electronic properties of the metal tungsten bronzes of high x value are interpreted in terms of a model in which the conduction electron wavefunctions are derived principally from the metal atomic p functions. It is shown that the physical properties of the bronzes are consistent with this model, which is compared, in this respect, with others. The transition to metallic conductivity at low x values is discussed, using the theory of Mott, and a number of experiments are suggested for clarifying some features of the electronic structure of the tungsten bronzes, and also of the related vanadium bronzes.Keywords
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