Magnetically linear and quadratic hexanitrocuprates

1 March 1979

journal article
research article
Published by AIP Publishing in Journal of Applied Physics

Vol. 50 (B3) , 1825-1827
https://doi.org/10.1063/1.327183

Abstract

Magnetic and caloric measurements on potassium lead hexanitrocuprate, K₂PbCu(NO₂)₆, agree well with the theory for an antiferromagnetic Heisenberg linear S=1/2 chain. Results for a related compound, in which lead is replaced by barium, can be analyzed in terms of an antiferromagnetic Heisenberg S=1/2 simple quadratic lattice. These classifications are supported by existing data on the crystal structures of these compounds at low temperatures.

This publication has 14 references indexed in Scilit:

Potassium strontium hexanitrocuprate(II) and potassium strontium hexanitronickelate(II)
Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials, 1976
Thermodynamics of magnetic chains with $S \leq \frac{5}{2}$
Physical Review B, 1976
The structure of two crystals of rubidium lead hexanitrocuprate(II)
Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials, 1976
Planar dynamic Jahn-Teller effects in nitrocomplexes: A single crystal neutron diffraction study of Cs2PbCu(NO2)6 at 293 K
Solid State Communications, 1975
JAHN‐TELLER‐induzierte Phasenübergänge bei den Hexanitro‐cupraten A₂PbCu(NO₂)₆[A = K, Rb, Cs]
Zeitschrift für anorganische und allgemeine Chemie, 1975
The heat capacities of linear Heisenberg chains
Physica, 1974
Structure of potassium calcium hexanitrocuprate(II) at 295.deg.K. Evidence for a static Jahn-Teller distortion
Journal of the American Chemical Society, 1974
Kooperative Jahn-Teller Effekte des Cu2+-Ions in Hexanitro-Komplexen vom Typ M2I[MIICu](NO2)6 (MI = K, Tl, Rb, Cs; MII = Ca, Sr, Pb, Ba) und Untersuchungen der Ni2+-Analoga
Journal of Solid State Chemistry, 1972
Redetermination of the crystal structure of potassium lead hexanitrocuprate(II), K2PbCu(NO2)6
Inorganic Chemistry, 1971
Linear Magnetic Chains with Anisotropic Coupling
Physical Review B, 1964