Stereocontrolled total synthesis of (±)-isocomene and (±)-β-isocomene via ring enlargement
- 1 January 1985
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 13,p. 898-899
- https://doi.org/10.1039/c39850000898
Abstract
A total synthesis of (±)-isocomene(1) and (±)-β-isocomene (2) employing a chelation-controlled regioselective epoxide–carbonyl rearrangement as the key step has been realized.Keywords
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