Cluster chemistry. Application of gold–oxonium reagents to the synthesis of poly-gold mixed-metal clusters: preparation and X-ray crystal structure of [Au3CoRu3(CO)12(PPh3)3], containing a bicapped trigonal-bipyramidal metal cluster
- 1 January 1982
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 20,p. 1141-1143
- https://doi.org/10.1039/c39820001141
Abstract
Reaction Between [{Au(PPh3)2}O][BF4] and [HCoRu3(CO)13] or [CoRu3(CO)13]– gives good yields of the title cluster which has been shown by an X-ray crystal structure analysis to have a seven-metal-atom skeleton, in which two gold atoms cap adjacent AuCoRu and AuRu2 faces of the trigonal bipyramidal AuCoRu3 core.Keywords
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