Synthesis and structure of [Ph4P]2[Cu6(S4)3S5],a polycyclic hexanuclear copper (I)cluster with complete sulphur co-ordination
- 1 January 1984
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 5,p. 314-315
- https://doi.org/10.1039/c39840000314
Abstract
The reaction of a methanolic CuI–thiolate solution with elemental sulphur yields deep-red[CU6(S4)3S5]2–which is the first hexanuclear CuIcluster with the complete sulphur co-ordination; the polycyclic anion can be regarded as an inorganic analogue of a corresponding mixed thiolate-sulphide complex and thus can serve as a possible model for cuI–thiolate sites in biological systems.Keywords
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