“Total Synthesis” Supramolecular Style: Design and Hydrogen-Bond-Directed Assembly of Ternary Supermolecules
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- 3 September 2001
- journal article
- research article
- Published by Wiley in Angewandte Chemie International Edition in English
- Vol. 40 (17) , 3240-3242
- https://doi.org/10.1002/1521-3773(20010903)40:17<3240::aid-anie3240>3.0.co;2-x
Abstract
Getting the right balance between intermolecular interactions is crucial for the synthesis of supermolecules in a preconceived manner. The three-component supermolecule (see picture) in the ternary cocrystal of 3,5-dinitrobenzoic acid, isonicotinamide, and 4-(dimethylamino)benzoic acid (1:1:1) assembles through a “primary” (between the stronger acid and pyridine) and a “secondary” hydrogen-bonding interaction (between the weaker acid and amide).Keywords
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