Aziridinolysis of (Triphenylphosphazenyl)pentachlorocyclotriphosphazene X-Ray Crystal Structure of N3P3 (NPPh3 )(NC2H4)5
Open Access
- 1 May 1984
- journal article
- Published by Walter de Gruyter GmbH in Zeitschrift für Naturforschung B
- Vol. 39 (5) , 615-617
- https://doi.org/10.1515/znb-1984-0514
Abstract
Reaction of aziridine with N3P3(NPPh3)Cl5 (1) affords the derivatives N3P3(NPPh3)Cl5-n(NC2H4)n (n = 1-5) whose structures are elucidated by NMR spectroscopy. The X-Ray crystal structure of N3P3(NPPh3)(NC2H4)5 shows a new conformation of the -NPPh3 group which would explain the upfield shift of the aziridino protons at the = P(NC2H4)(NPPh3)) siteKeywords
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