Photochemical Reaction of Tricarbonyl(η-methylcyclopentadienyl)manganese(I), [Mn(CO)3(MeCp)], with 1,1′-Bis(diphenylphosphino)ferrocene, (dppfe), and X-Ray Molecular Structure Analysis of [Mn(CO)(MeCp)(dppfe)]
- 1 July 1986
- journal article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 59 (7) , 2359-2361
- https://doi.org/10.1246/bcsj.59.2359
Abstract
Photochemical reaction of MeCpMn(CO)3 with (Ph2PC5H4)2Fe, (dppfe), was conducted in benzene. From the reaction mixture, the title compound [Mn(CO)(MeCp)(dppfe)] was isolated and its molecular structure was solved by X-ray analysis. ν(CO) peak at 1810 cm−1 of the title compound was clarified to be originated from the terminal carbonyl. Temperature-dependent 1H NMR spectra were also measured for the title compound.This publication has 7 references indexed in Scilit:
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